Today my friend asked question to me that where his Skype pic is stored. First of all, he were using Window 7 operating system. So i decide to make an quick guide on it for user convenience. Let see below steps.
Go to Start button and search
%appdata%\Skype then you will see
Skype folder choose and go inside.
Where you will see several folders, in which one of the name of the folder will be your Skype Username/ID. Go inside of this matched your ID folder name.
After go inside your username/ID folder, where find
Pictures named folder. That is the place where you captured Skype photos are being stored.